She's been an avid philanthropist ever since she first witnessed the crisis in war-torn Cambodia while filming Lara Croft: Tomb Raider in 2001.
And Angelina Jolie continued her humanitarian work as she attended the Fighting Stigma Through Film festival at the BFI in London on Friday evening.
The actress, 43, was joined at the event by Sophie, Countess of Wessex, and the women looked to be deep in conversation as they spoke together at the event.
Goodwill ambassador: Angelina Jolie looks elegant as she joins Sophie, Countess of Wessex at the Fighting Stigma Through Film festival for the Preventing Sexual Violence In Conflict initiative
Angelina looked elegant as she arrived at the goodwill event wearing a chic white dress, which she had cinched at the waist with a statement belt.
The Maleficent star added a glamorous flair to her ensemble with a lace undershirt, while she boosted her height in silver heels, while earlier on she wrapped up in a black longline coat.
Her brunette locks were styled in a slicked back style which allowed her hair to fall in loose waves over her shoulders and frame her face well.
Angelina highlighted her pretty features by wearing a slick of bright red lipstick, black eyeliner and smokey eye shadow.
Chic: Angelina made a stunning entrance at the event as she wore an white midi-dress, which she had cinched at the waist with a statement belt
Look wonderful in white like Angelina in Ralph & Russo
Whether she’s attending a high-profile event or simply running errands, Angelina Jolie always looks perfectly put together. Yesterday was no exception when the actress attended the Fighting Stigma Through Film festival.
She was donning an exquisite dress by Ralph & Russo, teamed with metallic accessories and a swipe of red lipstick. Created in supple silk, this elegant piece features an asymmetric wrap front, shawl neckline and midi length, ensuring it oozes luxury.
It actually comes with a rose gold detachable chain belt, but Angelina switched this to a pure white version to complement the dress.
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Regal: The royal looked demure in a navy blue coat, which she secured at the waist with a tightly knotted belt, and teamed up with a matching sleek shirt
Elegant: Sophie pulled her blonde locks back into a glamorous bun, while she brushed on a natural palette of make-up and accessorised with a pair of jewel earrings
Handsome: Angelina was also seen walking alongside fellow actor Chiwetel Ejiofor, 41, who looked dapper in a pair of denim jeans and a blue blazer, which he teamed up with a chequered shirt and grey scarf
The royal looked demure in a navy blue coat, which she secured at the waist with a tightly knotted belt, and teamed up with a matching sleek shirt.
Sophie pulled her blonde locks back into a glamorous bun, while she brushed on a natural palette of make-up and accessorised with a pair of jewel earrings.
Both women appeared to be in high spirits together, clearly getting on well as the Countess of Wessex patted her on the arm as they spoke with each other.
Angelina was seen walking alongside fellow actor Chiwetel Ejiofor, 41, who looked dapper in a pair of denim jeans and a blue blazer, which he teamed up with a chequered shirt and grey scarf.
While the actress was also spotted talking with Secretary of State for Foreign Affairs Jeremy Hunt, who spent much of the evening discussing the event alongside her.
Working together: While the actress was also spotted talking with Secretary of State for Foreign Affairs Jeremy Hunt
Talkative: Angelina could be seen talking with the politician during the event, who spent much of the evening alongside her
Giving a hand: Angelina and Jeremy were see clapping in the green room as they prepared for a Q&A at the launch event
Cosy: Earlier in the night, Angelina wrapped up in a black longline coat to keep off the winter chill
Beautiful: The actress looked happy as she arrived at the event and met with fans who waited for her outside the venue
Angelina is one of the key guests of the film festival, which aims to use the power of cinema to help fight and prevent discrimination faced by survivors of sexual violence in conflict.
The actress is also a co-founder of the Preventing Sexual Violence In Conflict initiative, which hosted the event.
38 films and documentaries will be screened over two days at the event, sharing the stories of survivors and inspiring others to work alongside them.
Leslie Thomas’ film The Prosecutors will have its world premiere at the festival, and other events include thought-provoking art installations, as well as organisations' showcases, and workshops led by prominent experts in the field.
Chic display: Angelina looked stunning as she left the film festival later that night
Stylish: The Maleficent star added a glamorous flair to her ensemble with a lace undershirt, while she boosted her height in silver heels
Important: Angelina is one of the key guests of the festival, which aims to use the power of cinema to help prevent discrimination faced by survivors of sexual violence in conflict
Special event: 38 films and documentaries will be screened over two days at the event, sharing the stories of survivors and inspiring others to work alongside them
To learn more: Other events include thought-provoking art installations, as well as organisations' showcases, and workshops led by prominent experts in the field
Angelina set up the Preventing Sexual Violence In Conflict initiative with William Hague in 2014, which has worked tirelessly to help those affected in countries like South Sudan and the Democratic Republic Of Congo.
Talking about the initiative on Friday, according to The Guardian Hague said to young filmmakers: 'We’ve made a tremendous start, but it’s only a start because as things stand, no member of Isil or Boko Haram or the armed forces of Burma has been brought to trial for crimes of sexual violence.'
The former foreign secretary added that it has been 'very difficult' to measure the success of the programme because of the scale of the problem, citing the 'tens of thousands of people raped in war in South Sudan'.
This is not the first humanitarian project the Malificent star has set up, as she opened a foundation, now called the Maddox Jolie-Pitt Foundation, in Cambodia in 2003.
The foundation acts as a conservation and community development program in the Samlout Protected Area.
Humanitarian: Angelina set up the Preventing Sexual Violence In Conflict initiative with William Hague in 2014, which has worked tirelessly to help those affected
Happy: Angelina seemed to be pleased with how the evening went as she left the film festival with a smile on her face
Good to see you: The actress turned director greeted fans who waited for her in the cold
Good sport: The actress made sure to make some time for her fans as she signed their memorabilia outside the venue
Keeping warm: Angelina walked out of the venue with her hands in her pockets as she stepped out into the cold night
Helping hand: This is not the first humanitarian project the Malificent star has set up, as she opened a foundation, now called the Maddox Jolie-Pitt Foundation, in Cambodia in 2003
Aims: The foundation acts as a conservation and community development program in the Samlout Protected Area
The UNHCR special envoy was also inspired by the country to make her Golden Globe nominated movie, First They Killed My Father.
Based on Cambodia human rights activist Luong Ung’s memoir, the film documents her experience as a young girl under the brutal rule of the Khmer Rouge.
Angelina spoke to Vanity Fair in 2017 about her first visit to the country, and said: 'I found a people who were so kind and warm and open, and, yes, very complex.
'You go there, and you see the families come out with their blanket and their picnic to watch a sunset,' she explained.
Angelina shares sons Maddox, 17, and Pax, 14, daughters Zahara, 13, and Shiloh, 12, and twins Knox and Vivienne, 10, with her ex-husband Brad Pitt.
Using film to make a change: The UNHCR special envoy was also inspired by the country to make her Golden Globe nominated movie, First They Killed My Father
Important message: Based on Cambodia human rights activist Luong Ung’s memoir, the film documents her experience as a young girl under the brutal rule of the Khmer Rouge
Doting mother: Angelina shares sons Maddox, 17, and Pax, 14, daughters Zahara, 13, and Shiloh, 12, and twins Knox and Vivienne, 10, with her ex-husband Brad Pitt
Friendly: Angelina waved goodbye to her fans as she left the event in a taxi after launching the event
Discussing the issue at hand: The actress attended a meeting at the Foreign Office with the Prime Minister's Special Envoy for Preventing Sexual Violence in Conflict, Lord Tariq Ahmad of Wimbledon
Stunning: Angelina looked glamorous in a blue midi dress and matching heels as she arrived at the Foreign Office
Fighting for change: Angelina was seen with The UN Secretary General's Special Representative on Sexual Violence in Conflict Pramila Patten at the meeting
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News Pictures Angelina Jolie looks elegant as she arrives at the Fighting Stigma Through Film festival in London
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